This capability is systems analyses for sustainable bioenergy cropping: analyses to provide guidance on how industries can calculate, measure, report, and verify their data on bioenergy crop collection and conversion, ensuring the credibility of incentives. LLNL’s Roads to Removal Study showcases this expertise in estimating bioenergy crop potential nationwide, while integrating complex system constraints (renewable energy, transportation, environment equity and justice). With high spatial resolution, we analyzed the systemic impacts of utilizing these bioenergy crops, including the production of various bioproducts such as SAF and H2 (up to 27 distinct pathways), while remove carbon to assist the US in achieving its net-zero climate goal. We include analysis of agronomic management (cover crops, tillage, amendments), future climate impacts, land availability, biodiversity and biogeochemical effects. We are actively involved in four MRV projects: an ‘umbrella’ project overseeing a comprehensive CDR MRV approach, and specific projects on BiCRS, mineralization, and cement production. For BiCRS MRV, we have expertise in emissions related to sustainable biomass sourcing and counterfactuals of biomass alternative fate. We are also developing new analytical methods and sensors for soil carbon MRV.